The reaction of Magnus green salt [Pt(NH3)4][PtCl4] in HClO4(1 M) with various (chloro)(hydroxo)PtIV complexes or with H2O2 gives a single phase partially oxidized conducting salt which contains directly interacting Pt atom chains (Pt–Pt 2.85 Å) adjacent to parallel chlorine bridged PtII–PtIV chains.
J. Catinat, T. Robert and G. Offergeld, J. Chem. Soc., Chem. Commun., 1983, 1310 DOI: 10.1039/C39830001310
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