Replacement of the 1,3-dithiolium carbene ligand by CO or F3CC![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
CCF3 in the complex [(triphos)Ni{CS2C2(CF3)2}][triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane] affords the complexes [(triphos)Ni(CO)] or [(triphos)Ni(F3CCCCF3)], whereas the 1,3-dithiolium carbene dimerizes to tetrakis(trifluoromethyl)tetrathiafulvalene.
C. Bianchini and A. Meli, J. Chem. Soc., Chem. Commun., 1983, 1309 DOI: 10.1039/C39830001309
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