Direct proof for the rearrangement of the prop-2-ynyl-lithium (2) into the propadienyl-lithium (4) is provided by the formation of the 1,3-disubstituted allenic compounds(7).
C. Huynh and G. Linstrumelle, J. Chem. Soc., Chem. Commun., 1983, 1133 DOI: 10.1039/C39830001133
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