Issue 20, 1983

A homoleptic arylmanganese(II) complex : synthesis and structure of a thermally stable trinuclear mesitylmanganese(II) complex

Abstract

The reaction of MnCl2 with mesMgBr (mes = 2,4,6-C6H2Me3) gave crystals of the linear trimer mes6Mn3 with bridging mesityl groups and the two end Mn atoms three-co-ordinated with a terminal mesityl; the Mn–C bond distances range from 2.10(1) to 2.35(1)Å and the Mn [dash dash, graph caption] Mn distance is 2.851(3)Å.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1128-1129

A homoleptic arylmanganese(II) complex : synthesis and structure of a thermally stable trinuclear mesitylmanganese(II) complex

S. Gambarotta, C. Floriani, A. Chiesi-Villa and C. Guastini, J. Chem. Soc., Chem. Commun., 1983, 1128 DOI: 10.1039/C39830001128

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