Issue 18, 1983

Silver catalysed macrocyclic ether formation: crystal structure of [(CH2O)6Ag2][Ag][AsF6]3

Abstract

Crystals containing the [(CH2O)6Ag2]2+ cation, which possesses approximate D3d symmetry with the two silver atoms each co-oriented by alternate oxygens of a novel twelve membered macrocyclic ether, were isolated from the reaction of (CH2O)3 with AgAsF6.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 981-982

Silver catalysed macrocyclic ether formation: crystal structure of [(CH2O)6Ag2][Ag][AsF6]3

H. W. Roesky, E. Peymann, J. Schimkowiak, M. Noltemeyer, W. Pinkert and G. M. Sheldrick, J. Chem. Soc., Chem. Commun., 1983, 981 DOI: 10.1039/C39830000981

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