Diastereoisomeric amides (9) and (10) are prepared by stereo selective aldol addition, followed by Claisen rearrangement; isomer (9) has been employed to synthesize hydrocarbon (14) and there by establish the stereostructure of the molecular fossil 13, 16-dimethyloctacosane-1,28-diol.
C. H. Heathcock and B. L. Finkelstein, J. Chem. Soc., Chem. Commun., 1983, 919 DOI: 10.1039/C39830000919
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