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Issue 15, 1983
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Structure and synthesis of cis-3,6-dibenzyl-3,6-bis(methylthio)-piperazine-2,5-dione, a new metabolite of Aspergillus terreus

Abstract

The titled compound (1b), the first naturally occurring, sulphur-containing dioxopiperazine unsubstituted on nitrogen, has been isolated from Aspergillus terreus and synthesised via the corresponding epidisulphide (2d), which has been tested as a biosynthetic precursor of bisdethiobis(methylthio)acetylaranotin (3).

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Article type: Paper
DOI: 10.1039/C39830000812
J. Chem. Soc., Chem. Commun., 1983, 812-813

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    Structure and synthesis of cis-3,6-dibenzyl-3,6-bis(methylthio)-piperazine-2,5-dione, a new metabolite of Aspergillus terreus

    G. W. Kirby, D. J. Robins and W. M. Stark, J. Chem. Soc., Chem. Commun., 1983, 812
    DOI: 10.1039/C39830000812

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