Issue 14, 1983

2,4,6,8-Tetrakis(N,N-di-isopropylamino)cyclotetraphosphoxane (Pri2NPO)4, a tetradentate ligand that chelates two metals: assemblage of a P4O4Mo2 cage structure

Abstract

Reaction of (Pri2N)2P(O)H with Mo(CO)6 resulted in deamination and formation of complex (1) which was characterized by X-ray analysis as [Pri2NPO]4Mo2(CO)8, a closo-P4O4Mo2 cage structure featuring a novel tetradentate phosphoxane ligand.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 776-777

2,4,6,8-Tetrakis(N,N-di-isopropylamino)cyclotetraphosphoxane (Pri2NPO)4, a tetradentate ligand that chelates two metals: assemblage of a P4O4Mo2 cage structure

E. H. Wong, M. M. Turnbull, E. J. Gabe, F. L. Lee and Y. Le Page, J. Chem. Soc., Chem. Commun., 1983, 776 DOI: 10.1039/C39830000776

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