The 1:1 complex between an osmate ester and bovine serum albumin was found to be effective as an enantioselective catalyst in the cis-hydroxylation of alkenes, affording diols in up to 68% e.e. and turnover of the catalyst with t-butyl hydroperoxide.
T. Kokubo, T. Sugimoto, T. Uchida, S. Tanimoto and M. Okano, J. Chem. Soc., Chem. Commun., 1983, 769 DOI: 10.1039/C39830000769
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