Replacement of the arene group in [Fe(η5-C5H5)(η6-C6H6–n-Men)]+(n⩽ 4) by three P(OMe)3 ligands is carried out under mild conditions by reductive electron transfer catalysis in acetonitrile and gives the free arene and [(η5-C5H5)Fe {P(OMe)3}3]+ in good yields.
A. Darchen, J. Chem. Soc., Chem. Commun., 1983, 768 DOI: 10.1039/C39830000768
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