Issue 13, 1983

Dehydrogenative vacuum pyrolysis: a novel synthetic technique. Conversion of cyclo-octa-1,5-diene into styrene and related reactions

Abstract

Vacuum pyrolysis in the presence of palladium on charcoal of the 3,3-dioxide (1) of 3-thiabicyclo[3.2.0]-heptane-6,7-dicarboxylic anhydride gave, without undesirable disproportionation, phthalic anhydride, also obtained from cis-2,3-divinylsuccinic anhydride (2) and cis-1,2,3,6-tetrahydrophthalic anhydride (5), while cyclo-octa-1,5-diene (7) and the disulphone (6) each gave styrene.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 725-726

Dehydrogenative vacuum pyrolysis: a novel synthetic technique. Conversion of cyclo-octa-1,5-diene into styrene and related reactions

C. M. Buchan, J. I. G. Cadogan, I. Gosney, B. J. Hamill, S. F. Newlands and D. A. Whan, J. Chem. Soc., Chem. Commun., 1983, 725 DOI: 10.1039/C39830000725

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