Vanadium hexacarbonyl undergoes disproportionation in the presence of several bases (L)(pyridine, tetrahydrofuran, diethyl ether, and acetonitrile) according to a second order rate law k[V(CO)6][L]; Fourier transform i.r. spectroscopic analysis of the reaction for L = pyridine reveals the presence of an isocarbonyl intermediate [(OC)6VCOV(L)4OCV(CO)5]en route to the ultimate product [V(L)6][V(CO)6]2.
T. G. Richmond, Q. Shi, W. C. Trogler and F. Basolo, J. Chem. Soc., Chem. Commun., 1983, 650 DOI: 10.1039/C39830000650
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