cpTiCl3(cp =η5-C5H5) in reaction with Me3SiN(H)R (R = Et, Pri, But, or Ph) yields the amido complexes cpTi(Cl)2N(H)R, which react further by HCl abstraction to give the corresponding centrosymmetric binuclear imido complexes [cp(Cl)Ti]2(µ-RN)2; substitution of the chloride ligands by organic groups is possible with the imido complexes, as is reversible reduction to stable anionic complexes.
C. T. Vroegop, J. H. Teuben, F. van Bolhuis and J. G. M. van der Linden, J. Chem. Soc., Chem. Commun., 1983, 550 DOI: 10.1039/C39830000550
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