Issue 9, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis, reactions, and crystal structures of cyclo-η5-[1-(disubstituted methyl)cyclopentadienyl](η-arene)-molybdenum and -tungsten compounds

Malcolm L. H. Green,   Alejandro Izquierdo,   Jesus J. Martin-Polo,   Victor S. B. Mtetwa  and  Keith Prout  

Abstract

The arene rings of W(η-C6H5Me)2 and Mo(η-C6H6)2 are readily displaced by the fulvenes C5H4[double bond, length half m-dash]CR2(R = Me or Ph) giving M(η5:η1-C5H4-µ-CR2)(η-arene), M = Mo or W; when M = Mo and R = Me then treatment with HCl gives the binuclear [Mo(η-PriC5H4)(µ-Cl2)]2 whose crystal structure has been determined and which is a convenient precursor to mono-cyclopentadienylmolybdenum derivatives.

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Article information

DOI
https://doi.org/10.1039/C39830000538
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 538-540

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Synthesis, reactions, and crystal structures of cyclo-η5-[1-(disubstituted methyl)cyclopentadienyl](η-arene)-molybdenum and -tungsten compounds

M. L. H. Green, A. Izquierdo, J. J. Martin-Polo, V. S. B. Mtetwa and K. Prout, J. Chem. Soc., Chem. Commun., 1983, 538 DOI: 10.1039/C39830000538

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