The impregnation of organic solutions of Pt3(µ-CO)3(PPh3)4 onto inorganic supports used for catalysis or chromatography has been shown to produce Pt5(µ-CO)5(PPh3)4, depending upon the nature of the support, its pre-treatment, and the solvent used; these observations are relevant to the preparation of cluster-derived catalysts.
R. Bender and P. Braunstein, J. Chem. Soc., Chem. Commun., 1983, 334 DOI: 10.1039/C39830000334
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