The monobenzo derivative (1) of 3a-methyl-3aH-indene and its methyl derivative (3) have been synthesised; although isolable they are reactive, undergoing autoxidation, dimerisation, and other [4 + 2]cycloadditions, thermal and acid catalysed aromatisation to fluorenes, and photochemical rearrangement to naphthalenes.
D. Neuhaus and C. W. Rees, J. Chem. Soc., Chem. Commun., 1983, 318 DOI: 10.1039/C39830000318
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