The photoisomerization of protonated 5-deuterio-5-methylhex-3-en-2-one to a protonated dihydrofuran is shown to occur with a specific 1,2 deuterium shift from C-5 to C-4.
R. F. Childs and G. S. Shaw, J. Chem. Soc., Chem. Commun., 1983, 261 DOI: 10.1039/C39830000261
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