Issue 4, 1983

Preparation and X-ray crystal structure of 3,3,5,5,9,9,11,11-octaphenyl-1,7-di-λ4-thia-2,4,6,8,10,12-hexa-aza-3,5,9,11-tetra-λ5-phosphabicyclo[5.5.0]dodecahexene: a twelve-membered inorganic heterocycle with a transannular sulphur–sulphur bond

Abstract

The reaction of the six-membered ring compound (Ph2PN)2NSCl with triphenylantimony is acetonitrile produces (Ph2PN)4(SN)2 shown by X-ray crystallography to consist of a twelve-membered ring with a transannular sulphur–sulphur bond.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 186-187

Preparation and X-ray crystal structure of 3,3,5,5,9,9,11,11-octaphenyl-1,7-di-λ4-thia-2,4,6,8,10,12-hexa-aza-3,5,9,11-tetra-λ5-phosphabicyclo[5.5.0]dodecahexene: a twelve-membered inorganic heterocycle with a transannular sulphur–sulphur bond

T. Chivers, M. N. S. Rao and J. F. Richardson, J. Chem. Soc., Chem. Commun., 1983, 186 DOI: 10.1039/C39830000186

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