Issue 4, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

The formation of a cyclohexadienone at a dimolybdenum centre; X-ray crystal structure of [Mo2(µ-{η4-CMe2·CH·CH·CH·C(But)CO})-(CO)2(η-C5H5)2], and evidence for an unusual bonding mode for a bridging 1,3-diene ligand

Michael Green,   A. Guy Orpen,   Colin J. Schaverien  and  Ian D. Williams  

Abstract

Reaction of [Mo2(CO)4(µ-CH·CH·CMe2)(η-C5H5)2] with ButC2H affords [Mo2(µ-{η4-[graphic omitted]O})(CO)2(η-C5H5)2] containing a bridging 1,3-diene ligand with an unusual bonding mode and an η3-allylic complex in which the Mo-Mo bond has been broken, whereas but-2-yne afords only the η3-allylic type of complex, and C2(CO2Me)2 gives a vinyl substituted µ-allylidene complex.

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Article information

DOI
https://doi.org/10.1039/C39830000181
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 181-183

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The formation of a cyclohexadienone at a dimolybdenum centre; X-ray crystal structure of [Mo2(µ-{η4-CMe2·CH·CH·CH·C(But)CO})-(CO)2(η-C5H5)2], and evidence for an unusual bonding mode for a bridging 1,3-diene ligand

M. Green, A. G. Orpen, C. J. Schaverien and I. D. Williams, J. Chem. Soc., Chem. Commun., 1983, 181 DOI: 10.1039/C39830000181

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