Deuterium n.m.r. studies have shown that α,β,β,3,4,5-hexadeuteriophenylalanine is incorporated into the dihydrophenanthrenoid phytoalexin orchinol with loss of aliphatic deuterium and an unexpected, and as yet unclarified, migration of aromatic deuterium.
A. Doux-Gayat, G. Défago, H. Kern, A. Stoessl and J. B. Stothers, J. Chem. Soc., Chem. Commun., 1983, 157 DOI: 10.1039/C39830000157
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