Determination of the mode of incorporation of [1-13C]- and [1,2-13C2]-acetate into oxytetracycline by Streptomyces rimosus, has established the exclusive polyketide origin of the tetracyclic nucleus and the direction of folding of a hypothetical linear intermediate.
R. Thomas and D. J. Williams, J. Chem. Soc., Chem. Commun., 1983, 128 DOI: 10.1039/C39830000128
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