Issue 2, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and structure of Mo3O9.4DMSO (DMSO = dimethyl sulphoxide): a novel chain structure

E. M. McCarron, III  and  R. L. Harlow, I  

Abstract

The reaction of MoO3.2H2 with DMSO (dimethyl sulphoxide) in a DMSO–H2O solution produces the crystalline compound Mo3O9.4DMSO which has been shown by X-ray diffraction to consist of infinite chains of molybdenum–oxygen polyhedra; the chemical repeat unit of the chain contains one tetrahedron [Mo(Ot)2(Ob)2] which bridges two octahedra [Mo{cis(Ot)2}(Ob)2(DMSO)2], where Ot and Ob represent terminal and bridging oxo-ligands, respectively.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39830000090
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 90-91

Permissions

Request permissions

Synthesis and structure of Mo3O9.4DMSO (DMSO = dimethyl sulphoxide): a novel chain structure

E. M. McCarron and R. L. Harlow, J. Chem. Soc., Chem. Commun., 1983, 90 DOI: 10.1039/C39830000090

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements