Perfluoroalkyl groups activate double-bonds towards cycloaddition reactions with diazomethane; a novel ring expansion is described, arising from a combination of eclipsing interactions and angle-strain.
M. R. Bryce, R. D. Chambers and G. Taylor, J. Chem. Soc., Chem. Commun., 1983, 76 DOI: 10.1039/C39830000076
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