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Issue 9, 1983
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Bis(2,9-diphenyl-1,10-phenanthroline)copper(I): a copper complex with a long-lived charge-transfer excited state

Abstract

The title compound, [Cu(dpp)2]+(dpp = 2,9-diphenyl-1,10-phenanthroline), exhibits long-lived emission at room temperature in solution, and in contrast with copper(I) complexes of less bulky ligands, the emission persists in polar media; a water soluble derivative of [Cu(dpp)2]+ is luminescent at room temperature in aqueous solution and undergoes efficient redox photochemistry in the presence of electron acceptors.

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Article information


J. Chem. Soc., Chem. Commun., 1983, 513-515
Article type
Paper

Bis(2,9-diphenyl-1,10-phenanthroline)copper(I): a copper complex with a long-lived charge-transfer excited state

C. O. Dietrich-Buchecker, P. A. Marnot, J. Sauvage, J. R. Kirchhoff and D. R. McMillin, J. Chem. Soc., Chem. Commun., 1983, 513
DOI: 10.1039/C39830000513

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