Issue 4, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Bridging phenoxo-ligands in dicopper(I) complexes: synthesis and structure of tetrakis(isocyanide)-bis(µ-phenoxo)-dicopper(I) complexes

Marco Pasquali,   Paolo Fiaschi,   Carlo Floriani  and  Amelia Gaetani-Manfredotti  

Abstract

The reaction of CuCl with PhONa followed by the addition of RNC (R = cyclohexyl, p-tolyl) gave as thermally stable crystalline solids [(RNC)4Cu2(OPh)2] containing a dicopper(I) unit doubly bridged by two phenoxo-groups [R =p-tolyl; Cu … Cu, 3.223(3)Å], with isocyanide ligands completing the tetraco-ordination around each copper [ν(C–N): R =p-tolyl, 2120 and 2145 cm–1; R = cyclohexyl, 2130 and 2160 cm–1].

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Article information

DOI
https://doi.org/10.1039/C39830000197
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 197-199

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Bridging phenoxo-ligands in dicopper(I) complexes: synthesis and structure of tetrakis(isocyanide)-bis(µ-phenoxo)-dicopper(I) complexes

M. Pasquali, P. Fiaschi, C. Floriani and A. Gaetani-Manfredotti, J. Chem. Soc., Chem. Commun., 1983, 197 DOI: 10.1039/C39830000197

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