An assignment of the lowest π-ionizations(1b1π) in thiophen, furan, and pyrrole at 12.5, 15.3, and 12.9 eV, respectively, is achieved by a comparison of observed HeII/HeI intensity changes in the corresponding photoelectron spectra with calculated intensity trends for different possible assignments.
L. Klasinc, A. Sabljić, G. Kluge, J. Rieger and M. Scholz, J. Chem. Soc., Perkin Trans. 2, 1982, 539 DOI: 10.1039/P29820000539
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