The molecular structures of the diequatorial and diaxial conformers of the syn- and anti-benzo[c]phenanthrene ‘fjord-region’ diol epoxide diastereoisomers have been determined by the Allinger force-field program. Certain features of steric crowding in the ‘fjord-region’ of the molecule that contribute to relative conformer stability are discussed.
B. D. Silverman and S. J. La Placa, J. Chem. Soc., Perkin Trans. 2, 1982, 415 DOI: 10.1039/P29820000415
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