New tetrahydronaphthacenequinones, which are related in structure to the aglycones of the antitumour drugs adriamycin and daunomycin, have been synthesised. Racemic daunomycinone has been prepared by a new, mild procedure utilising a phthalide intermediate for annelation.
M. J. Broadhurst and C. H. Hassall, J. Chem. Soc., Perkin Trans. 1, 1982, 2227 DOI: 10.1039/P19820002227
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