Lithium trialkylalkynylborates undergo unique Michael reactions involving migration of an alkyl group from boron to carbon. Oxidation or hydrolysis of the vinylboranes so produced yields compounds of synthetic potential. The generality and limitations of the Michael reactions are discussed.
A. Pelter, L. Hughes and J. M. Rao, J. Chem. Soc., Perkin Trans. 1, 1982, 719 DOI: 10.1039/P19820000719
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