Exchange of metal atoms in Ni(H2O)2Ni(CN)4·4H2O and Cs10SbVCl6(SbIIICl6)3
Abstract
The kinetics of the exchange of metal atoms in Ni(H2O)2 Ni(CN)4·4H2O and in Cs10 SbVCl6(SbIIICl6)3 have been investigated. The data for the former cannot be interpreted in terms of a combination of first-order processes: the data for the latter compound can. Treatments of this compound, with either ionising radiation or ultraviolet light before heating, alter the proportions, but not the energies of activation, of the various exchange channels.