The stable title compounds have been prepared by mercuriation of [M(CO)5(PPh2H)] using Hg[N(SiMe3)2]2 and characterized by 31P and 199Hg n.m.r. and mass spectroscopy. The values of 1J(31P–199Hg)(525–725 Hz) are the smallest observed so far for Hg–P bonds.
P. Peringer and J. Eichbichler, J. Chem. Soc., Dalton Trans., 1982, 667 DOI: 10.1039/DT9820000667
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