The thioxophosphoranesulphenyl bromides (1) act as ambident electrophiles towards alkenes and react, depending on the structure of the alkene, to give either the normal addition products –SC(R1)(R2)CR3(R4)(Br) or 1,2-dibromides and -disulphides.
A. Łopusinski, J. Michalski and M. Potrzebowski, J. Chem. Soc., Chem. Commun., 1982, 1362 DOI: 10.1039/C39820001362
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