The heterobimetallic complex trans-[{(η5-C5H5)2ZrCl(CH2PPh2)}2Rh(Co)Cl] has beeen prepared and found to react with CO to give unexpectedly the zirconium carbonyl complex [{(η5-C5H5)2Zr(CO)Cl(CH2PPh2)}2Rh-(CO)Cl]; an acyl complex is obtained when the uncomplexed {(η5-C5H5)2ZrCl(CH2PPh2)} reacts with Co.
R. Choukroun and D. Gervais, J. Chem. Soc., Chem. Commun., 1982, 1300 DOI: 10.1039/C39820001300
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