The spirobicyclic bisethlenedioxyphosphorane (1) undergoes ligand isomerization in the presence of methyl trifluoromethanesulphonate; this is an example of an irregular exchange involving a phosphonium ion intermediate.
G. McGall and R. A. McClelland, J. Chem. Soc., Chem. Commun., 1982, 1222 DOI: 10.1039/C39820001222
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