Issue 21, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and X-ray structure of [RuCo3(µ-CO)2(CO)7(µ-PPh2)(µ4-η2-ButC[triple bond, length half m-dash]CH)]: a novel heteronuclear butterfly cluster via the fragmentation of a phosphinoalkyne

Denis F. Jones,   Pierre H. Dixneuf,   Alain Benoit  and  Jean-Yves Le Marouille  

Abstract

The dehalogenation of [RuCl2(Ph2PC[triple bond, length half m-dash]CBut)(p-cymene)](1) by Co2(CO)8 and subsequent protonation afford the mixed metal cluster [RuCo3(µ4-η2-ButC[triple bond, length half m-dash]CH)(µ-PPh2)(CO)9](2) for which an X-ray structure determination has established the butterfly configuration of the RuCo3 species.

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Article information

DOI
https://doi.org/10.1039/C39820001217
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1217-1218

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Synthesis and X-ray structure of [RuCo3(µ-CO)2(CO)7(µ-PPh2)(µ4-η2-ButC[triple bond, length half m-dash]CH)]: a novel heteronuclear butterfly cluster via the fragmentation of a phosphinoalkyne

D. F. Jones, P. H. Dixneuf, A. Benoit and J. Le Marouille, J. Chem. Soc., Chem. Commun., 1982, 1217 DOI: 10.1039/C39820001217

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