Issue 20, 1982

New routes for the synthesis of estra-1,3,5(10)-triene-2,3,17β-triols-(catechol estrogens)

Abstract

2,3,17β-Tricetoxyestra-1,3,5(10)-triene has been prepared in good yields either from 2-chloromercurio-3-methyl-17β-acetoxyestra-1,3,5(10)-triene by a novel hydroboration–oxidation route or by oxidation of a previously unknown 2-organoboron substituted estradiol.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1157-1158

New routes for the synthesis of estra-1,3,5(10)-triene-2,3,17β-triols-(catechol estrogens)

E. Santaniello, A. Fiecchi and P. Ferraboschi, J. Chem. Soc., Chem. Commun., 1982, 1157 DOI: 10.1039/C39820001157

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