It is revealed by e.s.r. spectroscopy that the formation of many imidazolate-bridged binuclear copper(II) complexes of aminocarboxylates is pH-dependent with an apparent pKa of 8.3; this closely resembles an unusual pH-dependent property of zinc-free bovine erythrocyte superoxide dismutase.
H. Yokoi and M. Chikira, J. Chem. Soc., Chem. Commun., 1982, 1125 DOI: 10.1039/C39820001125
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