Reactivity of an α-acyl-α-cyclopropyl-carbenium ion: a highly stereoselective cyclopropylmethyl–cyclopropylmethyl rearrangement
Abstract
The complete stereoselectivity in a cyclopropylmethyl–cyclopropylmethyl rearrangement which has been investigated is rationalized in terms of a highly preferred conformation of the transient α-acyl-α-cyclopropyl-carbeium
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