The Rh6(CO)16–N,N,N,′N′-tetramethyl-1,3-propanediamine catalyst system has high activity for the reduction of aldehydes using CO and H2O as the hydrogen source; unsaturated aldehydes give the corresponding unsaturated alcohols in high yields.
K. Kaneda, M. Yasumura, T. Imanaka and S. Teranishi, J. Chem. Soc., Chem. Commun., 1982, 935 DOI: 10.1039/C39820000935
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