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Issue 14, 1982
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Evidence for a direct bonding interaction between titanium and a β-C–H moiety in a titanium–ethyl compound; X-ray crystal structure of [Ti(Me2PCH2CH2PMe2)EtCl3]

Abstract

The X-ray crystal structure of [Ti(Me2PCH2CH2PMe2)EtCl3](1) shows that the Ti–C–C angle and the Ti–C(methyl) distance of the Ti–Et moiety are 85.9(6)° and 2.516(10)Å, respectively and that the Ti–H–C (methyl) distances are 2.29(Ti–H) and 1.02(H–C)Å a direct bonding interaction between the titanium atom and the β-C–H system is proposed.

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Article information


J. Chem. Soc., Chem. Commun., 1982, 802-803
Article type
Paper

Evidence for a direct bonding interaction between titanium and a β-C–H moiety in a titanium–ethyl compound; X-ray crystal structure of [Ti(Me2PCH2CH2PMe2)EtCl3]

Z. Dawoodi, M. L. H. Green, V. S. B. Mtetwa and K. Prout, J. Chem. Soc., Chem. Commun., 1982, 802
DOI: 10.1039/C39820000802

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