Thermolysis of phenyl azide in the presence of sulphides bearing α-hydrogen atoms leads to the formation of significant amounts of 2-substituted anilines, presumably by Sommelet–Hauser type rearrangements of the intermediate N-phenylsulphimides.
L. Benati, M. Grossi, P. C. Montevecchi and P. Spagnolo, J. Chem. Soc., Chem. Commun., 1982, 763 DOI: 10.1039/C39820000763
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