SCHEDULED MAINTENANCE:
An X-ray crystal structure analysis of the title compound (1) shows the following notable features of the silacyclopropene ring ∠CSiC = 43.5(1)°, ∠SiCC = 69.8(1) and 66.7(1)°, C–C = 1.349(3), and Si–C = 1.800(2)(remarkably short) and 1.839(2) A; significant deviation of the ring from C2 symmetry may be due to the effect of substituents on the carbon atoms.
K. Hirotsu, T. Higuchi, M. Ishikawa, H. Sugisawa and M. Kumada, J. Chem. Soc., Chem. Commun., 1982, 726 DOI: 10.1039/C39820000726
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