Issue 13, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

The infrared vibrational assignment for the µ2-bridging methylene ligand in metal cluster complexes and its comparison with frequencies assigned to CH2 species chemisorbed on metal surfaces

Ian A. Oxton,   Donald B. Powell,   Norman Sheppard,   Kevin Burgess,   Brian F. G. Johnson  and  Jack Lewis  

Abstract

The infrared spectra of the metal cluster complexes (µ2-H)2Os3(CO)10(µ2-CH2) and Os3(CO)10(µ2-CO)(µ2-CH2) have been measured and assignments made of those vibrational modes which are associated with the methylene ligands; a comparison is made with frequencies earlier reported for this species adsorbed on W (110) and Ni (111) surfaces.

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Article information

DOI
https://doi.org/10.1039/C39820000719
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 719-721

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The infrared vibrational assignment for the µ2-bridging methylene ligand in metal cluster complexes and its comparison with frequencies assigned to CH2 species chemisorbed on metal surfaces

I. A. Oxton, D. B. Powell, N. Sheppard, K. Burgess, B. F. G. Johnson and J. Lewis, J. Chem. Soc., Chem. Commun., 1982, 719 DOI: 10.1039/C39820000719

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