Bis(carboxycyclopentadienyl) cobalt Co(C5H4CO2H)2+(1) and the cobalt(III) sepulchrate Co(sep)3– 9(2) produce hydrogen from water after single elecron reduction in an electrochemical process, and act as electron relays in photochemical hydrogen generating systems.
V. Houlding, T. Geiger, U. Kölle and M. Grätzel, J. Chem. Soc., Chem. Commun., 1982, 681 DOI: 10.1039/C39820000681
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