(±)-Phoracantholid I, a product from the secretion of the longicorn Phoracantha synonyma, has been synthesised via the caesium carbonate treatment of the methanesulphonate of 9-hydroxydecanoic acid, prepared from the easily accessible 9-oxo-derivative.
M. barbier, J. Chem. Soc., Chem. Commun., 1982, 668 DOI: 10.1039/C39820000668
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