Issue 12, 1982

Highly substituted dienes from butyne-1,4-diol. A one-flask synthesis and the mechanism of formation of 3-(N,N-diethylamino)-2-phenylsulphinylbutadiene

Abstract

When 4-acetoxybut-2-yn-1-ol is treated with benzenesulphenyl chloride and triethylamine, followed by diethylamine, 3-(N,N-diethylamino)-2-phenylsulphinylbutadiene is produced, in a multistep process, in 90% overall yield.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 665-666

Highly substituted dienes from butyne-1,4-diol. A one-flask synthesis and the mechanism of formation of 3-(N,N-diethylamino)-2-phenylsulphinylbutadiene

A. J. Bridges and J. W. Fischer, J. Chem. Soc., Chem. Commun., 1982, 665 DOI: 10.1039/C39820000665

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