The regiospecificity of incorporation of 2H from [1-13C,2-2H3]acetate into averufin by culturew of Aspergillus toxicarius has been determined using the β-2H isotope shift effect in 13C n.m.r. and by 2H n.m.r. spectroscopy; the results are discussed in relation to aflatoxin biosynthesis and polyketide biosynthesis in general.
T. J. Simpson, A. E. de Jesus, P. S. Steyn and R. Vleggaar, J. Chem. Soc., Chem. Commun., 1982, 632 DOI: 10.1039/C39820000632
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