It is shown that the internal distribution deuterium may considerably differ from the statistical distribution and that this property is exploitable, by quantitative 2H n.m.r. measurements, for investigating reaction mechanisms using isotopic labeling without the need for selective enrichment.
G. J. Martin, M. L. Martin, F. Mabon and M. Michon, J. Chem. Soc., Chem. Commun., 1982, 616 DOI: 10.1039/C39820000616
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