Issue 8, 1982

Reaction of allylsilanes and monothioacetals in the presence of Lewis acids: regioselectivity in the cleavage of the acetals

Abstract

Trimethylallylsilane reacts with monothioacetals in the presence of tin (IV) chloride, titanium tetrachloride, or boron trifluoride–diethyl ether to give the homoallyl ethers and homoallyl sulphides.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 459-460

Reaction of allylsilanes and monothioacetals in the presence of Lewis acids: regioselectivity in the cleavage of the acetals

H. Nishiyama, S. Narimatsu, K. Sakuta and K. Itoh, J. Chem. Soc., Chem. Commun., 1982, 459 DOI: 10.1039/C39820000459

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