Inorganic six-membered ring inversion. The inversion barrier in the tris(pentasulphane-1,5-diyl)platinate(IV) anion
Abstract
195 Pt N.m.r. studies of the ring inversion in the tris(pentasulphane-1,5-diyl)platinate(IV) anion reveal two conformations separated by a barrier(ΔG‡ at 273 K) of 50.5 ± 1.3 kJ mol–1.
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